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Technically a chemical weapon, but the point stands.
Hottest I ever had was a homegrown ghost pepper my uncle grew, it was hell
Capsaicin was literally evolved to be a chemical weapon. It's purpose is to deter mammals from eating them, but not birds.
Also, all fruit has evolved to be eaten. We didn't evolve to eat them.
Bhuto Jolokl , a strain of ghost pepper, was created to be weaponized by the Indian military
The dragons breath is inedible
I have tried every strain I have been able to find. The scorpion is very bad. Ghosts are ok, but dont have much of a taste.
The highest theoretical rating for a pepper on the Scoville scale is the rating of pure capisacin. In reality that can't be a pepper so it would have to be significantly lower than that. So probably 1.5 x the current hottest pepper is what is possible.
Also, the ghost pepper (buht jolokia) was used in pepper spray grenades by the Indian military.